西北大学主页平台管理系统焦林郁--中文主页-- Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed ortho C‒H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom

论文成果

当前位置: 中文主页 >> 论文成果

Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed ortho C‒H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom

点击次数：

影响因子：0.0
DOI码：10.1002/asia.201500829
发表刊物：Chemistry-An Asian Journal
关键字：alkenylation; C-H activation; crossdehydrogenative coupling; homogeneous catalysis; palladium
摘要：A phosphinic amide is introduced as a directing group for the ortho C−H alkenylation of anilines. The new donor group distinguishes itself from existing ones by assisting the C−H bond activation of anilides without (NH group) and with alkylation (NMe group) at the amide nitrogen atom. The reactivity is even reversed with the methyl‐substituted anilide being more reactive than its unsubstituted counterpart. Electron‐donating substituents at the arene ring enhance their reactivity while halogenation is not tolerated. The phosphinic amide also enables the C‐7‐selective C−H alkenylation of indoline.
论文类型：期刊论文
学科门类：理学
一级学科：化学
文献类型：J
卷号：11
页面范围：367-370
是否译文：否
收录刊物：SCI、EI、SSCI
第一作者：Lin-Yu Jiao

上一条：Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C‒H/C‒H Arylation of Indolines at the C-7 Position under Air

下一条：Copper catalyzed synthesis of aryl/alkyl mixed phosphates from diphenylphosphoryl azides and aliphatic alcohols under mild conditions

个人信息

焦林郁Linyu Jiao

同专业博导

同专业硕导

论文成果

Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed ortho C‒H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom