焦林郁Linyu Jiao

教授

 博士生导师  硕士生导师
学位:博士学位
性别:男
毕业院校:柏林工业大学
学历:博士研究生毕业
在职信息:在职
所在单位:化工学院
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Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C‒H/C‒H Arylation of Indolines at the C-7 Position under Air

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影响因子:0.0
DOI码:10.1021/ol503035z
发表刊物:Organic Letters
摘要:An improved method for the dehydrogenative C-H/C-H cross-coupling at the C-7 position of indolines containing a urea as a directing group is reported. The new protocol is a rare example of an aerobic palladium(II)-catalyzed cross dehydrogenative coupling (CDC) reaction that proceeds at low temperature. The use of either Cu(OAc)2 in an open flask or dioxygen (balloon) at 50 °C tolerates indolines not substituted at C-2 and C-3, thereby extending the scope of the previous method that suffers from indoline-to-indole oxidation.
论文类型:期刊论文
学科门类:理学
一级学科:化学
文献类型:J
卷号:16
页面范围:6020–6023
是否译文:
收录刊物:SCI、EI、SSCI
第一作者:Lin-Yu Jiao