影响因子：0.0
DOI码：10.1016/j.jcat.2019.09.014
发表刊物：Journal of Catalysis
关键字：Copper catalysisDPPAAliphatic alcoholAryl/alkyl mixed phosphatesEsterificationMechanistic study
摘要：An efficient and convenient one-pot protocol is developed to prepare aryl/alkyl mixed phosphates in the presence of copper catalyst under exceptionally mild conditions. A series of versatile, ubiquitous, and inexpensive phosphoryl azides and aliphatic alcohols are combined for the first time ever. Diphenylphosphoryl azide is employed as novel phosphors reagent through an unexpected cleavage of PN bond. The transformation is advantageous with respect to a broad of functional group compatibility and different esterification products are isolated in good to excellent results. This new catalytic system represents a superior platform towards a mild, operationally simple, practical, and scalability alternative to access target molecules. Furthermore, a plausible mechanism is proposed based on insightful mechanistic studies.
学科门类：工学
一级学科：化学工程与技术
文献类型：J
卷号：379
期号：1
页面范围：39-45
是否译文：否
收录刊物：SCI、EI、SSCI
第一作者：Lin Yu Jiao