影响因子：0.0
DOI码：10.1016/j.catcom.2019.105889
发表刊物：Catalysis Communications
关键字：Mesoionic carbenePEPPSIN-heterocyclic carbene1,2,3-Triazol-5-ylideneBidentate palladium(II) complexArylation
摘要：A novel PEPPSI (pyridine enhanced precatalyst preparation stabilization and initiation) type palladium(II) complex has been synthesized and fully characterized by NMR, HR-MS, as well as elemental analysis. The molecular structure was finally confirmed by single crystal X-ray diffraction, and it revealed that the pyridyl-armed 1,2,3-triazole ligand is coordinated to the palladium in bidentate fashion. This air and moisture insensitive complex has proven to be a suitable catalyst for the arylation of pyridine N-oxides and 2-bromopyrroles with a broad functional group tolerance, demonstrating that the robustness and high efficiency of our complex.
论文类型：期刊论文
学科门类：理学
一级学科：化学
文献类型：J
卷号：135
期号：1
页面范围：105889
是否译文：否
收录刊物：SCI、EI、SSCI
第一作者：Lin-Yu Jiao