Linyu Jiao
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Exceptionally Mild Palladium(II)-Catalyzed Dehydrogenative C‒H/C‒H Arylation of Indolines at the C-7 Position under Air
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DOI number:10.1021/ol503035z

Journal:Organic Letters

Abstract:An improved method for the dehydrogenative C-H/C-H cross-coupling at the C-7 position of indolines containing a urea as a directing group is reported. The new protocol is a rare example of an aerobic palladium(II)-catalyzed cross dehydrogenative coupling (CDC) reaction that proceeds at low temperature. The use of either Cu(OAc)2 in an open flask or dioxygen (balloon) at 50 °C tolerates indolines not substituted at C-2 and C-3, thereby extending the scope of the previous method that suffers from indoline-to-indole oxidation.

Indexed by:Journal paper

Discipline:Natural Science

First-Level Discipline:Chemistry

Document Type:J

Volume:16

Page Number:6020–6023

Translation or Not:no

Included Journals:SCI、EI、SSCI

First Author:Lin-Yu Jiao

Personal information

Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates

Name (English):Linyu Jiao

Name (Pinyin):jiaolinyu

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School/Department:School of Chemical Engineering

Administrative Position:Professor

Education Level:With Certificate of Graduation for Doctorate Study

Business Address:Room 517, School of Chemical Engineering

Gender:Male

Contact Information:+86-(0)15029011564

Degree:Doctoral degree

Status:Employed

Alma Mater:Technical University of Berlin

Discipline:Other specialties in Chemical Engineering and Technology
Chemical Engineering

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Honors and Titles:

仲英青年学者  2020-01-03

国家建设高水平大学公派研究生奖学金  2011-05-10

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