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DOI number:10.1002/asia.201500829
Journal:Chemistry-An Asian Journal
Key Words:alkenylation; C-H activation; crossdehydrogenative coupling; homogeneous catalysis; palladium
Abstract:A phosphinic amide is introduced as a directing group for the ortho C−H alkenylation of anilines. The new donor group distinguishes itself from existing ones by assisting the C−H bond activation of anilides without (NH group) and with alkylation (NMe group) at the amide nitrogen atom. The reactivity is even reversed with the methyl‐substituted anilide being more reactive than its unsubstituted counterpart. Electron‐donating substituents at the arene ring enhance their reactivity while halogenation is not tolerated. The phosphinic amide also enables the C‐7‐selective C−H alkenylation of indoline.
Indexed by:Journal paper
Discipline:Natural Science
First-Level Discipline:Chemistry
Document Type:J
Volume:11
Page Number:367-370
Translation or Not:no
Included Journals:SCI、EI、SSCI
First Author:Lin-Yu Jiao
Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Name (English):Linyu Jiao
Name (Pinyin):jiaolinyu
E-Mail:
School/Department:School of Chemical Engineering
Administrative Position:Professor
Education Level:With Certificate of Graduation for Doctorate Study
Business Address:Room 517, School of Chemical Engineering
Gender:Male
Contact Information:+86-(0)15029011564
Degree:Doctoral degree
Status:Employed
Alma Mater:Technical University of Berlin
Discipline:Other specialties in Chemical Engineering and Technology
Chemical Engineering
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Honors and Titles:
仲英青年学者 2020-01-03
国家建设高水平大学公派研究生奖学金 2011-05-10
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