Linyu Jiao
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Oxidative Palladium(II)-Catalyzed C-7 Alkenylation of Indolines
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DOI number:10.1021/ol402687t

Journal:Organic Letters

Abstract:A mild procedure for C-7-selective CH alkenylation of various indolines under oxidative palladium(II) catalysis is reported. A fully substituted urea, formed by carbamoylation of the indoline nitrogen atom, functions as a directing group. Both R,β-unsaturated acceptors and styrenes participate in this direct CH functionalization. With a free NH group at the urea terminus, the nitrogen atom subsequently cyclizes in a 1,4-fashion to yield a six-membered ring.

Indexed by:Journal paper

Discipline:Natural Science

First-Level Discipline:Chemistry

Document Type:J

Volume:15

Page Number:5374–5377

Translation or Not:no

Included Journals:SCI、EI、SSCI

First Author:Lin-Yu Jiao

Personal information

Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates

Name (English):Linyu Jiao

Name (Pinyin):jiaolinyu

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School/Department:School of Chemical Engineering

Administrative Position:Professor

Education Level:With Certificate of Graduation for Doctorate Study

Business Address:Room 517, School of Chemical Engineering

Gender:Male

Contact Information:+86-(0)15029011564

Degree:Doctoral degree

Status:Employed

Alma Mater:Technical University of Berlin

Discipline:Other specialties in Chemical Engineering and Technology
Chemical Engineering

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Honors and Titles:

仲英青年学者  2020-01-03

国家建设高水平大学公派研究生奖学金  2011-05-10

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