焦林郁Linyu Jiao

教授

 博士生导师  硕士生导师
学位:博士学位
性别:男
毕业院校:柏林工业大学
学历:博士研究生毕业
在职信息:在职
所在单位:化工学院
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Regioselective deoxygenative chalcogenation of 7-azindole N-oxides promoted by I2/PEG-200

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发表刊物:Organic & Biomolecular Chemistry
摘要:We developed a general and sustainable approach for the regioselective deoxygenative chalcogenation of 7-azindole N-oxides; the combination of an internal oxidant and a green solvent has been used successfully for the synthesis of mono- and dichalcogenyl 7-azaindoles which are of pharmaceutical interest. The regioselectivity is tunable by the variation of the reaction conditions. I2/PEG was established as an efficient and reusable catalytic system for C–H chalcogenation. This developed methodology has great potential for practical utility, with a broad substrate scope, green reaction conditions, and operational simplicity.
论文类型:期刊论文
学科门类:理学
一级学科:化学
文献类型:J
卷号:17
页面范围:10073–10087
是否译文:
收录刊物:SCI、SSCI