影响因子:0.0
    
    
    
     发表刊物:Organic & Biomolecular Chemistry
    
    
    
     摘要:We developed a general and sustainable approach for the regioselective deoxygenative chalcogenation of 7-azindole N-oxides; the combination of an internal oxidant and a green solvent has been used successfully for the synthesis of mono- and dichalcogenyl 7-azaindoles which are of pharmaceutical interest. The regioselectivity is tunable by the variation of the reaction conditions. I2/PEG was established as an efficient and reusable catalytic system for C–H chalcogenation. This developed methodology has great potential for practical utility, with a broad substrate scope, green reaction conditions, and operational simplicity.
    
     论文类型:期刊论文
    
     学科门类:理学
     一级学科:化学
     文献类型:J
     卷号:17
    
     页面范围:10073–10087
    
    
     是否译文:否
    
    
     收录刊物:SCI、SSCI
    

