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DOI number:10.1016/j.catcom.2019.105889
Journal:Catalysis Communications
Key Words:Mesoionic carbenePEPPSIN-heterocyclic carbene1,2,3-Triazol-5-ylideneBidentate palladium(II) complexArylation
Abstract:A novel PEPPSI (pyridine enhanced precatalyst preparation stabilization and initiation) type palladium(II) complex has been synthesized and fully characterized by NMR, HR-MS, as well as elemental analysis. The molecular structure was finally confirmed by single crystal X-ray diffraction, and it revealed that the pyridyl-armed 1,2,3-triazole ligand is coordinated to the palladium in bidentate fashion. This air and moisture insensitive complex has proven to be a suitable catalyst for the arylation of pyridine N-oxides and 2-bromopyrroles with a broad functional group tolerance, demonstrating that the robustness and high efficiency of our complex.
Indexed by:Journal paper
Discipline:Natural Science
First-Level Discipline:Chemistry
Document Type:J
Volume:135
Issue:1
Page Number:105889
Translation or Not:no
Date of Publication:2019-10-09
Included Journals:SCI、EI、SSCI
First Author:Lin-Yu Jiao
Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Name (English):Linyu Jiao
Name (Pinyin):jiaolinyu
E-Mail:
School/Department:School of Chemical Engineering
Administrative Position:Professor
Education Level:With Certificate of Graduation for Doctorate Study
Business Address:Room 517, School of Chemical Engineering
Gender:Male
Contact Information:+86-(0)15029011564
Degree:Doctoral degree
Status:Employed
Alma Mater:Technical University of Berlin
Discipline:Other specialties in Chemical Engineering and Technology
Chemical Engineering
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Honors and Titles:
仲英青年学者 2020-01-03
国家建设高水平大学公派研究生奖学金 2011-05-10
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