郭兆琦副教授

副教授 硕士生导师

出生日期：

电子邮箱：

入职时间：

所在单位：化工学院

学历：博士研究生毕业

办公地点：长安校区化工学院911室

性别：男

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学位：博士学位

在职信息：在职

主要任职：

其他任职：

毕业院校：中国科学院理化技术研究所

所属院系：

   
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个人简介

    西北大学副教授，研究生导师，入选陕西省青年人才计划。2010年毕业于中国科学院理化技术研究所。2010年7月至2014年4月先后在日本自然科学研究机构分子科学研究所和大阪大学从事博士后研究工作。2014-2017年7月在西安近代化学研究所工作，2017年8月进入西北大学化工学院。主持完成国家自然科学基金青年项目1项，横向课题4项；主持在研陕西省自然科学基础研究重点项目1项、国防重点实验室基金2项及横向课题2项。发表论文三十余篇，担任多个SCI期刊审稿人，《火炸药学报》青年编委。课题组隶属西安市特种能源材料重点实验室，主要从事特种能源材料的开发及应用研究，具体涉及有机多孔材料（COFs, CTFs, POPs），金属-有机框架材料（MOFs），微纳米有机-无机杂化材料等。欢迎化学工程，应用化学，材料与化工专业的有志青年加入课题组。

  

部分研究论文(*为通讯作者)

38. Xiao Wang, Hui Li, Yanjing Yang, Yefeng Wang, Shuai Liu, Jinyuan Zhang, Jiandong Yang, Yang Zhang, Haixia Ma, Zhaoqi Guo*, Surface-Hydrophobic Al@COFs Core-Shell structured Composites: A class of efficient high-energy fuels, Fuel, 2024, 371, 131943.

37. Zhi Qu , Shuai Liu, Yefeng Wang, Jiandong Yang, Yang Zhang, Jinyuan Zhang, Yutong Gao, Haixia Ma, and Zhaoqi Guo*, Enhanced Photocatalytic Activity of Calix[4]arene-Based Donor–Acceptor Covalent Organic Frameworks by Dual Cocatalysts, ACS Applied Polymer Materials 2024, 6, 8, 4756–4768.

36. Hao Wang, Lanting Shi, Zhi Qu, Lingfeng Zhang, Xiao Wang, Yefeng Wang, Shuai Liu, Haixia Ma, Zhaoqi Guo*，Increasing Donoracceptor Interactions and Particle Dispersibility of Covalent Triazine Frameworks for Higher Crystallinity and Enhanced Photocatalytic Activity，ACS Applied Materials & Interfaces, 2024, 16, 2296−2308. 

35. Lingfeng Zhang, Yu Wang, Yefeng Wang, Shuai Liu, Na Zhang, Mingmin Yang, Haixia Ma and Zhaoqi Guo*, N-Methylene-C bridged tetrazole and 1,2,4- triazole energetic salts as promising primary explosives, CrystEngComm, 2024, 26, 143.

34. Lijiang Guan, Zhaoqi Guo, Qi Zhou, Jin Zhang, Cheng Cheng, Shengyao Wang, Xiang Zhu, Sheng Dai & Shangbin Jin，A highly proton conductive perfluorinated covalent triazine framework via low-temperature synthesis，Nature Communications 2023, 14, 8114. https://www.nature.com/articles/s41467-023-43829-4

33. Tingting Lei, Ke-Juan Meng, Na Yang, Qi-Long Yan*, Xiaolong Fu*, Haixia Ma, and Zhaoqi Guo*, Gas-Phase Synthesis of Perfluoroalkyl-Functionalized Graphene and Its Desensitization Effect on 1,3,5,7-Tetranitro-1,3,5,7-Tetraazacyclooctane, ACS Appl. Nano Mater. 2023, https://doi.org/10.1021/acsanm.3c01623

32. Jiawei Liu , Tingting Lei, Yuxin Xue, Xiao Wang, Qi-long Yan, Xiaolong Fu, Haixia Ma, and Zhaoqi Guo*，Modulation of Crystal Growth of an Energetic Metal–Organic Framework on the Surfaces of Graphene Derivatives for Improved Detonation Performance. Langmuir, 2022, 38, 48, 14959–14968. https://doi.org/10.1021/acs.langmuir.2c02743

31. Hao Wang, Lijiang Guan, Jiawei Liu,  Tingting Lei, Yuxin Xue, Zhi Qu, Shangbin Jin* , Haixia Ma, Zhaoqi Guo*，A Thiazolo[5,4-d]thiazole Functionalized Covalent Triazine Framework Showing Superior Photocatalytic Activity for Hydrogen Production and Dye Degradation，Journal of Materials Chemistry A, 2022, 10, 16328-16336. IF 14.511

30. Jianhua Yi, Zhao Qin, Haijian Li, Fengqi Zhao, Haixia Ma, Zhaoqi Guo*, Reactive molecular dynamics study on the thermal decomposition reaction of a triple-base solid propellant, Journal of Molecular Modeling, 2022, 28: 216. https://rdcu.be/cRqIP

29. Wang, Yu; Zheng, Wanwan; Zhang, Lingfeng; Ma, Haixia*; Zhang, Yazhou; Guo, Zhaoqi*, Constructing planar C−N bond-linked bi-triazole high-energy explosives via the formation of salts, Bulletin of the Chemical Society of Japan, 2022, 95,898-908 doi:10.1246/bcsj.20220060

28. Xiang Chen, Cong Zhang, Wenli Cao, Zhaoqi Guo*, Jianguo Zhang, Haixia Ma*, Searching for high performance asymmetrically substituted teterazine energetic materials based on 3-hydrazino-6-(1H-1,2,3,4-tetrazol-5-ylimino)-s-tetrazine, Arabian Journal of Chemistry, 2022, https://doi.org/10.1016/j.arabjc.2022.103880

27. Zhaoqi Guo, Yu Wang, Yazhou Zhang and Haixia Ma*, Energetic Host–guest Inclusion Compounds: An Effective Design Paradigm for High-energy Materials. CrystEngComm, 2022, 24, 3667-3674. https://doi.org/10.1039/D2CE00171C

26. Yu Wang, Jin Ye, Na Yang, Haixia Ma*, Yazhou Zhang, Zhaoqi Guo*. Strong Intermolecular Interactions Induced Methylene-Bridged Asymmetric Heterocyclic Explosives. CrystEngComm, 2021, 23, 7635–7642. DOI: 10.1039/D1CE01083B

25. Yu Wang, Siyu Xu, Heng Li, Haixia Ma,* Yazhou Zhang and Zhaoqi Guo*. Laser Ignition of Energetic Complexes: Impact of Metal Ion on Laser Initiation Ability. New Journal of Chemistry, 2021, 45, 12705-12710.

24. Jiachen Li, Chi Zhang, Huijun Ma, Taihe Wang, Zhaoqi Guo, Yong Yang, Yaoyu Wang*, Haixia Ma*, Modulating interfacial charge distribution of single atoms confined in molybdenum phosphosulfide heterostructures for high efficiency hydrogen evolution, Chemical Engineering Journal, 2021, 414: 128834. https://doi.org/10.1016/j.cej.2021.128834

23. Yanfei Cheng, Xiang Chen, Na Yang, Yazhou Zhang, Haixia Ma, Zhaoqi Guo*, Sandwich-like Low-sensitive Nitroamine Explosives Stabilized by Hydrogen Bonds and π-π Stacking Interactions, CrystEngComm, 2021, 23, 1953-1960. DOI: 10.1039/D0CE01882A

22. Xiang Chen, Zhaoqi Guo, Cong Zhang, Rong Gao, Jianguo Zhang, Haixia Ma*, Constructing 3D layered energetic metal-organic framework with strong stacking interactions of hydrogen-bridged rings: the way to insensitive high energy complex, CrystEngComm, 2020, 22, 5436-5446. DOI: 10.1039/D0CE00643B

21. Wei He, Wen Ao, Guangcheng Yang, Zhijian Yang, Zhaoqi Guo, Pei-Jin Liu*, Qi-Long Yan*, Metastable Energetic Nanocomposites of MOF-activated Aluminum Featured with Multi-Level Energy Releases, Chemical Engineering Journal, 2020, 381: 122623. https://doi.org/10.1016/j.cej.2019.122623

20. Xue-Xue Zhang, Wei He, Shu-Wen Chen, Jie-Yao Lyu, Zhaoqi Guo*, Michael Gozin* & Qi-Long Yan*, Tuning the crystal morphology and catalytic behavior of graphene-templated energetic bis-tetrazole copper coordination polymers, Advanced Composites and Hybrid Materials, 2019, 2(2): 289-300. https://doi.org/10.1007/s42114-019-00085-9

19. Xuemin Hou, Zhaoqi Guo, Liqiang Yang, Haixia Ma*, Four Three-Dimensional Metal-organic Frameworks assembled from 1H-tetrazole: Synthesis, Crystal Structures and Thermal Properties, Polyhedron, 2019, 160: 198-206. https://doi.org/10.1016/j.poly.2018.12.035

18. Zhaoqi Guo*, Yu Wang, Xuemin Liu, Cong Zhang, Yazhou Zhang, Haixia Ma*, “Auxiliary ligand-directed synthesis of 3D energetic coordination polymer from discrete complex: enhanced energy density, thermal stability and energy performance”, CrystEngComm, 2019, 21, 462-469, DOI: 10.1039/C8CE01891J

17. Ting Zhang, Yu Guo, Jiachen Li, Yulei Guan, Zhaoqi Guo, Haixia Ma*, High Catalytic Activity of Nitrogen-Doped Graphene on the Thermal Decomposition of CL-20, Propellants, Explosives, Pyrotechnics, 2018, 43(12): 1263-1269. https://doi.org/10.1002/prep.201800014

16. Xiang Chen, Tian Zeng, Cong Zhang, Zhaoqi Guo, Shuailei Li, Tao Mai, Rong Gao & Haixia Ma*, Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid, Chemical Research in Chinese Universities, 2018, 34(6): 959-964.

15. Zhaoqi Guo*, Xuemin Liu, Xiang Chen, Cong Zhang, Guoping Yang, Yazhou Zhang, Haixia Ma*, Design and synthesis of two energetic coordination polymers based on copper ion and 1H,1′H-[5,5′-bitetrazole]-1,1′-diol: A comparative study of the structure-property relationships, Journal of Solid State Chemistry, 2018, 268, 55–61. https://doi.org/10.1016/j.jssc.2018.08.030

14. X. Chen, C. Zhang, Y. Bai, Z. Guo, Y. Yao, J. Song and H. Ma, Synthesis, crystal structure and thermal properties of an unsymmetrical 1,2,4,5-tetrazine energetic derivative, Acta Crystallographica Section C: Structural Chemistry, 2018, 74(6): 666-672. https://doi.org/10.1107/S2053229618006617

13. Jie Li, Huiyu Liua, Zhaoqi Guo, Mingyan Yang, Jirong Song and Haixia Ma*, Two Cu(II)-triadimenol complexes as potential fungicides: Synergistic actions and DFT calculations, RSC advances, 2018, 8(6): 2933-2940. DOI: 10.1039/C7RA10572J

12. Zhaoqi Guo*, Yunlong Wu, Chongqing Deng, Guoping Yang*, Jiangong Zhang, Zhihua Sun, Haixia Ma, Chao Gao, Zhongwei An, Structural Modulation from 1D Chain to 3D Framework: Improved Thermostability, Insensitivity, and Energies of Two Nitrogen-Rich Energetic Coordination Polymers, Inorganic chemistry, 2016, 55, 11064-11071, https://doi.org/10.1021/acs.inorgchem.6b01630

11. Mitsuharu Suzuki, Zhaoqi Guo, Kazukuni Tahara, Juliet F. Khosrowabadi Kotyk, Huan Nguyen, Jun Gotoda, Kohei Iritani, Yves Rubin, and Yoshito Tobe “Self-Assembled Dehydro[24]annulene Monolayers at the Liquid/Solid Interface: Toward On-Surface Synthesis of Tubular π-Conjugated Nanowires”, Langmuir, 2016, 32 (22), 5532–5541 (equal contribution), https://doi.org/10.1021/acs.langmuir.6b00744

10. Zhaoqi Guo, Kazukuni Tahara, Koji Inukai, Hiroshi Takeda, Masahiro Kouno, Kohei Iritani, and Yoshito Tobe*, Effect of Multiple Interactions on Face-On vs Edge-On Configurations of Butadiyne-Bridged Octadehydrodibenzo[12]annulene Derivatives at the Liquid/Graphite Interface, The Journal of Physical Chemistry C, 2015, 119(28): 15977-15981. https://doi.org/10.1021/acs.jpcc.5b02569

9. Xiong Chen, Matthew Addicoat, Enquan Jin, Lipeng Zhai, Hong Xu, Ning Huang, Zhaoqi Guo, Lili Liu, Stephan Irle,  Donglin Jiang, “Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity”, J. Am. Chem. Soc., 2015, 137 (9), 3241-3247

8. Xiaoming Liu, Yanhong Xu, Zhaoqi Guo, Atsushi Nagai and Donglin Jiang, “Super absorbent conjugated microporous polymers: a synergistic structural effect on the exceptional uptake of amines” Chem. Commun., 2013, 49, 3233-3235

7. Atsushi Nagai, Xiong Chen, Xiao Feng, Xuesong Ding, Zhaoqi Guo and Donglin Jiang. “A squaraine-linked mesoporous covalent organic framework” Angew. Chem. Int. Ed., 2013, 52, 3770-3774

6. Zhao-Qi Guo, Wei-Qiang Chen, and Xuan-Ming Duan. “Seven-membered ring excited-state intramolecular proton-transfer in 2-benzamido-3- (pyridin-2-yl)acrylic acid.” Dyes and Pigments, 2012, 92, 619-625

5. Atsushi Nagai, Zhaoqi Guo, Xiao Feng, Shangbin Jin, Xiong Chen, Xuesong Ding and Donglin Jiang. “Pore surface engineering in covalent organic frameworks.” Nature Communications, 2:536 doi: 10.1038/ncomms1542 (2011)

4. Yanhong Xu, Long Chen, Zhaoqi Guo, Atsushi Nagai and Donglin Jiang. “Light-Emitting Conjugated Polymers with Microporous Network Architecture: Interweaving Scaffold Promotes Electronic Conjugation, Facilitates Exciton Migration, and Improves Luminescence” J. Am. Chem. Soc., 2011, 133 (44), 17622–17625

3. Yan Kou, Yanhong Xu, Zhaoqi Guo and Donglin Jiang. “Supercapacitive energy storage and electric power supply using an aza-fused conjugated microporous framework.” Angew. Chem. Int. Ed., 2011, 50, 8753-8757

2. Long Chen, Yong Yang, Zhaoqi Guo and Donglin Jiang. “Highly efficient activation of molecular oxygen with nanoporous metalloporphyrin frameworks in heterogeneous systems.” Adv. Mater., 2011, 23, 3149–3154

1. Zhao-Qi Guo, Wei-Qiang Chen, and Xuan-Ming Duan. “Highly selective visual detection of Cu(II) utilizing intramolecular hydrogen bond-stabilized merocyanine in aqueous buffer solution.” Org. Lett., 2010, 12, 2202-2205

教育经历

[1]   2005.9-2010.7

中国科学院理化技术研究所  |  有机化学  |  理学博士学位  |  博士研究生毕业

[2]   2001.9-2005.7

西北大学  |  化学  |  理学学士学位  |  大学本科毕业

研究方向

  • [1]  特种能源材料

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    团队名称：西安市特种能源材料重点实验室