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DOI number:10.1021/ol503035z
Journal:Organic Letters
Abstract:An improved method for the dehydrogenative C-H/C-H cross-coupling at the C-7 position of indolines containing a urea as a directing group is reported. The new protocol is a rare example of an aerobic palladium(II)-catalyzed cross dehydrogenative coupling (CDC) reaction that proceeds at low temperature. The use of either Cu(OAc)2 in an open flask or dioxygen (balloon) at 50 °C tolerates indolines not substituted at C-2 and C-3, thereby extending the scope of the previous method that suffers from indoline-to-indole oxidation.
Indexed by:Journal paper
Discipline:Natural Science
First-Level Discipline:Chemistry
Document Type:J
Volume:16
Page Number:6020–6023
Translation or Not:no
Included Journals:SCI、EI、SSCI
First Author:Lin-Yu Jiao
Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Name (English):Linyu Jiao
Name (Pinyin):jiaolinyu
E-Mail:
School/Department:School of Chemical Engineering
Administrative Position:Professor
Education Level:With Certificate of Graduation for Doctorate Study
Business Address:Room 517, School of Chemical Engineering
Gender:Male
Contact Information:+86-(0)15029011564
Degree:Doctoral degree
Status:Employed
Alma Mater:Technical University of Berlin
Discipline:Other specialties in Chemical Engineering and Technology
Chemical Engineering
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Honors and Titles:
仲英青年学者 2020-01-03
国家建设高水平大学公派研究生奖学金 2011-05-10
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