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DOI number:10.1016/j.jcat.2019.09.014
Journal:Journal of Catalysis
Key Words:Copper catalysisDPPAAliphatic alcoholAryl/alkyl mixed phosphatesEsterificationMechanistic study
Abstract:An efficient and convenient one-pot protocol is developed to prepare aryl/alkyl mixed phosphates in the presence of copper catalyst under exceptionally mild conditions. A series of versatile, ubiquitous, and inexpensive phosphoryl azides and aliphatic alcohols are combined for the first time ever. Diphenylphosphoryl azide is employed as novel phosphors reagent through an unexpected cleavage of PN bond. The transformation is advantageous with respect to a broad of functional group compatibility and different esterification products are isolated in good to excellent results. This new catalytic system represents a superior platform towards a mild, operationally simple, practical, and scalability alternative to access target molecules. Furthermore, a plausible mechanism is proposed based on insightful mechanistic studies.
Discipline:Engineering
First-Level Discipline:Chemical Engineering and Technology
Document Type:J
Volume:379
Issue:1
Page Number:39-45
Translation or Not:no
Included Journals:SCI、EI、SSCI
First Author:Lin Yu Jiao
Pre One : Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed ortho C‒H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom
Next One : 1,2,3-Triazol-5-ylidene bearing a pyridine auxiliary based bidentate PEPPSI type palladium(II) complex: Synthesis, structure, and application in the direct arylation of pyridine N-oxide
Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Name (English):Linyu Jiao
Name (Pinyin):jiaolinyu
E-Mail:
School/Department:School of Chemical Engineering
Administrative Position:Professor
Education Level:With Certificate of Graduation for Doctorate Study
Business Address:Room 517, School of Chemical Engineering
Gender:Male
Contact Information:+86-(0)15029011564
Degree:Doctoral degree
Status:Employed
Alma Mater:Technical University of Berlin
Discipline:Other specialties in Chemical Engineering and Technology
Chemical Engineering
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PostalAddress :
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Honors and Titles:
仲英青年学者 2020-01-03
国家建设高水平大学公派研究生奖学金 2011-05-10
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